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Season 12, Episode 10 - "Foreign Exchange" When Josh finds an outlaw operation in Brazil, he gets a hands-on lesson in how quickly he can turn sugar cane into high-proof liquor. In Maggie Valley, Mike and Jerry prepare to fight back when Richard and Craig start a backwoods operation on their turf.

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Season 12, Episode 09 - On the run from the law, Josh motors deep into the Brazilian highlands in search of a new recipe for caffeinated cachaça moonshine.

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Season 12, Episode 07-08 - "Still Imploder" In a rare lapse of judgment, Richard implodes Daniel’s $3,000 copper still. As the fire marshal ramps up his investigation, Josh makes a tough decision to flee the country. Tim’s solution to a centuries-old still build is going to sting a bit for Howard.

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Season 12, Episode 00 - "Overhaul in Overalls" With tons of shine to sell, Josh and Tickle attempt to buy a car from an off-duty cop and turn it into a bootlegging vehicle; as sparks fly, Tickle’s challenge turns to keeping Josh from setting it on fire.

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Season 12, Episode 06 - "Rock Out While the Cop's Out" Mark and Digger score ten tons of sugar only to find a tracking device on their truck; Richard and Daniel devise a rum recipe to dominate the outlaw market; Mike and Jerry hit the jackpot with sweet-smelling mimosa liquor.

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Season 12, Episode 05 - "Hell-Bent Detective" A police detective confronts Mark and Digger at the pump and doesn't mince words about his intent; Tickle and the Laws attempt to help as Josh's sanity erodes surviving in the woods.

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Season 12, Episode 04 - "Long Arm of Kenny Law" Fed up with canned food and hiding in the woods, Josh gets into trouble with Kenny Law. Popcorn's son proves as unpredictable as his notorious dad. Tim and Howard rediscover a lost recipe for log still whiskey invented by a Kentucky teenager in 1836.

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Season 12, Episode 03 - "More Cops Less Copper" Evading the law, Mark and Digger attempt to make Scotch on a Popcorn Sutton-designed pot still. Amanda joins Mark and Huck in the hills only to find all their copper stolen. Richard and Daniel deploy game cameras to protect their own valuable stills.